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CR-Scientific


A look at
Chemophobia


by Christian Thorsten

For the article "Chemical Safety", please click here.


There was a time when it was common for every budding scientist to go to the drugstore and buy chemicals. 
The pharmacist would size his customer up pretty quickly-- if he thought the person was an idiot or a klutz, then no chemicals.  Otherwise one could come home with a big bottle of formaldehyde solution, a jar of potassium dichromate, or a host of other things to help explore the wonders of science.
There was a time when parents raised children, instead of letting television do it for them.
Gradually, however, the notion appeared that people had to be protected from their own carelessness and ignorance.  This fostered an incredibly toxic idea:  if anything bad at all happened to a person, it must be someone else's fault.   Right on its heels was another, equally toxic idea:  if a few people did something bad, everyone should be punished. 
Pharmacists slowly quit selling "the good stuff" to junior chemists. 
This writer remembers an increasingly-common type of encounter:  "Do you carry _______?"  The whole place would grow silent.  A nearby lady-- complete with fur coat, two or three pearl necklaces, and too much makeup-- would emit a sound of shocked disgust.  In the most haughtily-condescending voice she could muster, she warned, "Chemicals are dangerous, young man."  Though her sparkling gems of chemical knowledge had been gleaned almost entirely from the New York Times, her authoritative tone gave her credibility in the eyes of other store patrons.
Difficulty building a chemistry set may seem to certain readers a small price to pay, but it's a symptom of a much greater damage done to science in general.  
It's easy to be cavalier with someone else's pastime, but consider it this way:  attempting to ban golf clubs because they're sometimes used in murders and assaults would make little sense, and it would upset a great many legitimate golfers.  Statistically, there are dozens of common and not-so-common things that far overshadow chemistry for the number of injuries or deaths they produce-- but those things are not subject to the level of irrational fear related to all things chemical.
The high importance one might assign to golf doesn't make for a good argument, either.  On the scale of importance, chemistry wins every time.  While the writer may be going out on a limb here, he's pretty sure there are many, many more hobby chemists who go on to become professionals than there are hobby golfers who turn pro.  Golf and bicycling are sports.  Chemistry is the central science on which nearly everything in our modern society depends.  As a matter of fact, a great many of the discoveries which underpin our modern society came from amateur experimenters working on their own time, not from an elite priesthood sequestered away in some ivory tower.  Despite increasing public prejudice against individual chemists, society depends a great deal on discoveries made by lone, amateur experimenters.  People like to point out Leonardo DaVinci's genius and his wonderful contributions to science.  Ironically, they fail to recall how public outrage at the time would have had the man lynched, if only the common people and the authorities had known what DaVinci was doing in his "clandestine" lab.   In DaVinci's day, the lingering dark-age mentality would have had him burned at the stake for dissecting cadavers (now a standard exercise in all medical schools).  A new type of dark-age thinking, spawned for different reasons, is becoming unfortunately common.
Another misconception is that "everything that could be discovered easily already has been".  This couldn't be farther from the truth.  It is still entirely possible for an individual to run across phenomena that science hasn't adequately explored.  These discoveries don't always require mass spectrometers or million-dollar grants.   Moreover, a vast body of knowledge has been forgotten or perhaps lies buried in some German or French scientific journal from the 1860's.  Every scientist seems to have a citation with the journal's abbreviation;   nobody seems to know the full title of the thing;  and no library seems actually to have a copy (sometimes the citations don't even point to the right article, because nobody has ever actually found the journal...).  Who knows what useful advances could arise from re-exploring this early work, now that the average amateur has more technology at her disposal than did the entire world of the 19th Century?
Something attracts chemists consistently.  It's very important to recognize what this is.  People become chemists because they like chemistry, not because they randomly picked it from a list of careers or because they think it will lead them to riches or fame.  In turn, they like chemistry because something introduced them to it.  What introduced them to chemistry was, much more often than not, seeing a spectacular demonstration and then going on to do their own experiments.
Science is crucial to maintaining a nation's vitality and its industrial base;  when the supply of budding scientists diminishes, everyone suffers eventually.  If you pick any random person on the street and ask him what he thinks of "chemicals", it will often be mistrust or even outright fear.  The same person finds no irony in the fact that he wears clothes, eats food, and drives a car.
A great many chemists, this writer included, became interested in the science because of its sheer "wow" factor.  Now, the "wow" factor has ceased to exist for many.   Would-be chemists are now told in school to do these experiments in their "imaginations".  They get discouraged quickly and often give up science for life.  Ultimately, that is society's loss. 
Something is grievously wrong when we as a society can turn out legions of disenfranchised youth, street gangs, and broken families-- often without giving it a second thought-- but chemistry gets people uncomfortable. 
The rising industrial powers of Asia put great importance on chemistry and other basic sciences, as any rising industrial power must.  They also don't have the stifling, litigious, chemophobic atmosphere so common in many Western nations.  It becomes obvious who will ultimately take the crown of industrial supremacy.
Compounding the problem is the gross overreaction on the part of lawmakers and others who have criminalized or severely restricted certain chemicals.  The reasoning is always the same:  a few people misuse them, so let's restrict them for  everyone.  Good examples are red phosphorus and iodine.  When outlawing the possession or sale of methamphetamine proved unable to fix the problem, someone thought it might be a good idea to restrict a couple of reagents that are very useful in general chemistry.  When a normal person claims he doesn't know of "any legitimate reason" to possess these chemicals, that's just harmless ignorance.  When someone ordained with power of arrest says the same thing, it is no longer harmless.
In a just society, buying iodine crystals and red phosphorus would no more make someone a drug cook than buying gasoline would make someone an arsonist.  Worse, now we have legislators who for some reason think it's a good idea to control the sale of baking soda.  That's just ridiculous.
Phobias are all the same, in a way.  The irrational fear of something becomes so much more debilitating than the thing itself.  If the phobia sufferer happens to be aggressive, that phobia will affect others who want no part of it.
It is very difficult to outlaw high places, spiders, and large bodies of water.  One imagines that if it were possible, those would be illegal too.

The distillation apparatus and the three-necked flask-- symbols of the noble and dignified profession of chemistry-- have been twisted by the chemophobes into the basest tools of fear-mongering. 
Some people who ought to know better have aided and abetted the chemophobes with their actions or words.  Sometimes it's subtle.
A Wikipedia article, evidently written by a chemist (i.e., someone who should know better), claims that "any distillation procedure is extremely hazardous" (underlined, no less!).
That's ridiculous.
Only a few kinds of distillation are "extremely" hazardous.  Most are only moderately so.


Chemicals are an unavoidable and necessary part of every person's life. It's true that some laboratory chemicals, when handled improperly, can cause injury or death, but there are varying degrees of hazard (as you'll see browsing through the MSDS for various chemicals- though some MSDS writers got carried away with their over-use of capital letters).  It's all about magnitudes. 
There is a dangerous, public misconception that chemicals in general are 'evil'.  Lawmakers, having once been members of the public themselves, bring their misconceptions with them to places they shouldn't.
The news media, largely ignorant of chemistry, have only fueled the fire-- after all, hysteria gets ratings.  Assigning evil qualities to inanimate objects is a hallmark of primitive societies dominated by low intelligence, yet it routinely comes from people who in all other respects are fairly smart.  In the common way of thinking, the word "chemical" has become an emotionally-loaded word.  The word "synthetic" is looked upon with suspicion, at best.  Conversely, "natural" is often thought of as inherently harmless.
Cyanide is natural.  
This writer occasionally jokes that people should be required to get an MSDS sheet and live in fear of a dozen regulations every time they buy a stick of butter or even a gallon of water.  (Enough of this silliness would cause modern society to grind to a halt, perhaps making people realize the frank absurdity of chemophobia).  According to more than one study, cooking butter-- actually, fats in general--   releases several compounds that are hazardous by ingestion and inhalation.  Hexane and toluene are just two of these.  Accidentally overheat that butter and you also end up with acrolein, which is even worse.  There's potential DNA damage, cancer, and reproductive harm-  all from natural foods. 

For all the time the author has spent working with hazardous chemicals over the years, it was an ordinary tuna sandwich that caused the most harrowing experience.  It appears there were either bacterial toxins or toxic breakdown products of protein (e.g., histamine), possibly both.  No amount of chemophobia, nor environmental impact studies, nor bumptious old ladies from the drugstore could have prevented this incident.
A sandwich doesn't even have a warning label.  On the other hand, people have been injured or killed for doing something they really had no excuse to do:  failing to read warning labels that clearly stated the hazards.   This has happened with power tools, ladders, stairs, bicycles, buckets, automobiles, and household cleaners. 

Banning "chemicals" makes some uninformed people "feel better", but this can be at everyone else's expense rather than benefit.  Often it seems they don't even know what it is they're banning. 
There is class of chemicals that includes alkyl sulfonates and aryl-alkyl sulfonates.  These have killed numerous pets and people, especially small children.  To demonstrate their deadliness, one can take a water solution of these compounds and pour them on some grease ants.  The ants will die within seconds-- often, faster than they would from ant poison.  Alkyl and aryl sulfonates can disrupt cell membranes and therefore are fundamentally dangerous to living things.
Should we form a committee to ban these chemicals?
They are the detergents we use every day. 
The deaths are easy to prevent:  not by banning detergents and making everyone wear dirty clothes and eat from dirty dishes, but by keeping detergents in a locked cabinet when toddlers and pets are around. 
A carpenter's hammer is a very dangerous weapon.  You don't pull it out of the toolbox and smash yourself one, though, do you?  I didn't think so.  A hammer is safe to use in some ways, but not in others.   To expect unconditional safety-- to demand some way to make everything perfectly safe under all conditions-- is to be dangerously out of touch with reality.
Despite the best intentions of those who want to make our world safer, there will never be such thing as a "non-toxic house" or a "non-toxic workplace".  Even the oxygen in the air you breathe would kill us if it weren't for certain enzymes in the body-- and in fact, oxygen eventually kills us anyway.  How about water?  Too much of that's not safe, either.  Water can disrupt electrolyte balances, and we all know what it does when it's inhaled. 
If people don't stop bandying about the phrases "highly toxic" and "extremely hazardous" in connection with everything under the sun, they'll soon demean the phrase to the point where it's useless.  The same goes for "deadly", "poisonous", and so forth.
The constrictive atmosphere that has grown out of chemophobia seems difficult to stem, because several factors have entrenched it very deeply within our present socio-economic framework.   However, educating the public is certainly within reach of even the average citizen.


Chemical Safety, Part I

Chemical Safety, Part II



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